Equilibrium: JEE Mains 2022 June 29 Shift 2

Hard· Law of mass action, Kc and Kp· +4 / −1
4.04.0 moles of argon and 5.05.0 moles of PCl5\mathrm{PCl_5} are introduced into an evacuated flask of 100100 litre capacity at 610 K610\ \text{K}. The system is allowed to equilibrate. At equilibrium, the total pressure of the mixture was found to be 6.0 atm6.0\ \text{atm}. The KpK_p for the reaction PCl5⇌PCl3+Cl2\mathrm{PCl_5\rightleftharpoons PCl_3+Cl_2} is [Given : R=0.082 L atm K−1mol−1R=0.082\ \text{L atm K}^{-1}\text{mol}^{-1}]
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